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Huang Chi
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Personal Information
  • Supervisor of Doctorate Candidates
  • Supervisor of Master's Candidates
  • Name (Pinyin):Huang Chi
  • E-Mail:
  • Administrative Position:Professor
  • Education Level:研究生毕业
  • Business Address:化学与分子科学学院
  • Gender:Male
  • Contact Information:++86-27-68754226
  • Status:Employed
  • Alma Mater:Wuhan University
  • Teacher College:School of Chemistry and Molecular Sciences
  • Honors and Titles
      2023  elected:2023年度湖北省科技进步奖三等奖. 医用水溶性高分子PVP自由基聚合关键技术、成套设备及产业化
      2020  elected:湖北省双创战略团队A类负责人
      2019  elected:湖北省双创战略团队B类负责人
      2018  elected:湖北省双创战略团队C类负责人
      2012  elected:江苏省双创人才
      2011  elected:武汉市东湖高新技术开发区“3551光谷人才”
      2017  elected:首批“全国万名优秀创新创业导师人才库”
      2017  elected:甲基芳烃氨氧化的高效长寿面催化剂的研制与工业化应用. 中国石油与化学工业联合会技术发明三等奖
      2016  elected:取代甲苯氨氧化的含钒复合氧化物催化剂的研制与应用. 湖北省技术发明二等奖
      2014  elected:科研反哺教学 培养化学创新人才. 第七届国家高等学校教学成果二等奖
      2013  elected:科研反哺教学 培养化学创新人才. 湖北省高等学校教学成果一等奖
      2005  elected:理科化学类专业化工课程体系和教学内容改革研究. 度湖北省高等学校教学成果一等奖.
      2005  elected:《大学化学实验》.湖北省多媒体课件二等奖
      2003  elected:含碳官能团有机硅化合物的研究、开发与产业化. 湖北省科技进步一等奖
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Paper Publications
Current position: Home   >   Scientific Research   >   Paper Publications

Oriented Assembled Prussian Blue Analogue Framework for Confined Catalytic Decomposition of Ammonium Perchlorate

  • Date of Publication:2023-02-13
  • Hits:

  • Impact Factor: 

    13.3

  • Journal: 

    Small

  • Key Words: 

    ammonium perchlorate, catalytic mechanism, confined catalytic, decomposition kinetics, Prussian blue

  • Abstract: 

    The design of highly dispersed active sites of hollow materials and unique contact behavior with the components to be catalyzed provide infinite possibilities for exploring the limits of catalyst capacity. In this study, the synthesis strategy of highly open 3-dimensional frame structure Prussian blue analogues (CoFe-PBA) was explored through structure self-transformation, which was jointly guided by template mediated epitaxial growth, restricted assembly and directional assembly. Additionally, good application prospect of CoFe-PBA as combustion catalyst was discussed. The results show that unexpected thermal decomposition behavior can be achieved by limiting AP(ammonium perchlorate) to the framework of CoFe-PBA. The high temperature decomposition stage of AP can be advanced to 283.6 °C and the weight loss rate can reach 390.03% min-1. In-situ monitoring shows that CoFe-PBA can accelerate the formation of NO and NO2. The calculation of reaction kinetics proved that catalytic process was realized by increasing the nucleation factor. On this basis, the catalytic mechanism of CoFe-PBA on the thermal decomposition of AP was discussed, and the possible interaction process between AP and CoFe-PBA during heating was proposed. At the same time, another interesting
    functional behavior to prevent AP from caking was discussed.

  • Co-author: 

    Tang Xiaolin,Ren Zhuoqun,Zheng Zeyu,Zhang Kuan,Zhou Rui,Wu Dan,Liao Jun

  • Indexed by: 

    Journal paper

  • Correspondence Author: 

    Zhang Yifu*,Huang Chi *

  • Document Type: 

    J

  • Volume: 

    19

  • Issue: 

    20

  • Page Number: 

    2207023

  • ISSN No.: 

    1613-6810

  • Translation or Not: 

    no

  • Date of Publication: 

    2023-01-15

  • Included Journals: 

    SCI

  • Links to published journals: 

    https://doi.org/10.1002/smll.202207023

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