个人信息Personal information
- 博士生导师
- 硕士生导师
- 教师拼音名称:Huang Chi
- 电子邮箱:
- 所在单位:化学与分子科学学院
- 职务:教授
- 学历:研究生毕业
- 办公地点:化学与分子科学学院
- 性别:男
- 联系方式:+86-27-68754226
- 在职信息:在职
- 毕业院校:武汉大学
- 所属院系:化学与分子科学学院
联系方式Contact information
论文成果
PC基电解液对Li/CrOx一次电池高倍率性能的影响
发表时间:2024-05-17 点击次数:
影响因子:10.6
DOI码:10.3866/pku.whxb202308053
发表刊物:物理化学学报
刊物所在地:中国
摘要:In the wake of the carbon–neutral era, the exploration of innovative materials for energy storage and conversion has garnered increasing attention. While nickel silicates have been a focal point in energy storage research, their application in supercapacitors (SCs) has been relatively underreported due to poor conductivity. A newly designed architecture, designated as rGO@NiSiO@NiO/C (abbreviated for reduced graphene oxide (rGO), nickel silicate (NiSiO), nickel oxide/carbon (NiO/C)), has been developed to enhance the electrochemical performance of NiSiO. The incorporation of inner rGO provides structural support for NiSiO, enhancing conductivity, while the outer NiO/C layer not only boosts conductivity but also safeguards NiSiO from structural degradation and electrolyte dissolution. This architecture eliminates multi-phase mixtures, facilitating rapid electron/mass transfer kinetics and accelerating electrochemical reactions, resulting in exceptional electrochemical properties. The rGO@NiSiO@NiO/C architecture achieves a specific capacitance of 324F⋅g− 1 at 0.5 A⋅g− 1, with a superb cycle performance of ~ 91 % after 10,000 cycles, surpassing state-of-the-art nickel silicates. Furthermore, the hybrid supercapacitor (HSC) device incorporating the rGO@NiSiO@NiO/C electrode attains an areal capacitance of 159 mF⋅cm− 2 at 2.5 mA⋅cm− 2, a retention ratio of ~ 98 % after 10,000 cycles, and an energy density of 0.68
合写作者:李惠,孟庆飞,李文杰,吴际良,方永进
论文类型:期刊论文
通讯作者:黄驰*,曹余良*
论文编号:2308053
学科门类:理学
文献类型:J
卷号:40
期号:9
页面范围:2308053
是否译文:否
发表时间:2024-09-01
收录刊物:SCI