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In situ synthesis of ultrafine metal clusters triggered by dodecaborate supramolecular organic frameworks

  • Date:2018-11-03
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  • Affiliation of Author(s): 

    化学与分子科学学院

  • Journal: 

    Nanoscale

  • Place of Publication: 

    英国

  • Abstract: 

    Supramolecular nano-assemblies with tunable morphology have attracted extensive attentions in many frontiers and composite materials manufacturing. Herein, a new class of shape-controlled dodecaborate-based supramolecular organic frameworks (BOFs), decorated with diverse ultrafine noble metal clusters (Au, Pd, Pt, Ag), have been successfully fabricated via the tunable host-guest assembly of cucurbit[n=5,6,7,8]uril and Cs2[closo-B12H12]. Benefiting from the unique dodecaborate-cucurbit[n]uril chaotropic effect, a breakthrough has been made in modulating the supramolecular frameworks in the urch

  • Indexed by: 

    Journal paper

  • Document Code: 

    DOI: 10.1039/C8NR06917D

  • Discipline: 

    Natural Science

  • First-Level Discipline: 

    Chemistry

  • Document Type: 

    J

  • Issue: 

    10

  • Page Number: 

    19846 – 19853

  • Translation or Not: 

    no

  • Date of Publication: 

    2018-10-15

  • Included Journals: 

    SCI
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