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Huang Chi
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Personal Information
  • Supervisor of Doctorate Candidates
  • Supervisor of Master's Candidates
  • Name (Pinyin):Huang Chi
  • E-Mail:
  • Administrative Position:Professor
  • Education Level:研究生毕业
  • Business Address:化学与分子科学学院
  • Gender:Male
  • Contact Information:++86-27-68754226
  • Status:Employed
  • Alma Mater:Wuhan University
  • Teacher College:School of Chemistry and Molecular Sciences
  • Honors and Titles
      2023  elected:2023年度湖北省科技进步奖三等奖. 医用水溶性高分子PVP自由基聚合关键技术、成套设备及产业化
      2020  elected:湖北省双创战略团队A类负责人
      2019  elected:湖北省双创战略团队B类负责人
      2018  elected:湖北省双创战略团队C类负责人
      2012  elected:江苏省双创人才
      2011  elected:武汉市东湖高新技术开发区“3551光谷人才”
      2017  elected:首批“全国万名优秀创新创业导师人才库”
      2017  elected:甲基芳烃氨氧化的高效长寿面催化剂的研制与工业化应用. 中国石油与化学工业联合会技术发明三等奖
      2016  elected:取代甲苯氨氧化的含钒复合氧化物催化剂的研制与应用. 湖北省技术发明二等奖
      2014  elected:科研反哺教学 培养化学创新人才. 第七届国家高等学校教学成果二等奖
      2013  elected:科研反哺教学 培养化学创新人才. 湖北省高等学校教学成果一等奖
      2005  elected:理科化学类专业化工课程体系和教学内容改革研究. 度湖北省高等学校教学成果一等奖.
      2005  elected:《大学化学实验》.湖北省多媒体课件二等奖
      2003  elected:含碳官能团有机硅化合物的研究、开发与产业化. 湖北省科技进步一等奖
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Paper Publications
Current position: Home   >   Scientific Research   >   Paper Publications

Interaction Between Prussian Blue Ultrathin Nanosheet and Ammonium Perchlorate for Highly Efficient Thermal Decomposition

  • Date of Publication:2023-02-19
  • Hits:

  • Impact Factor: 

    19.0

  • DOI number: 

    10.1002/adfm.202300661

  • Journal: 

    Advanced Functional Materials

  • Key Words: 

    ammonium perchlorate, catalytic mechanisms, decomposition kinetics, Prussian blue, structural transformations

  • Abstract: 

    Catalytic stability is the prerequisite for the catalyst to achieve high catalytic efficiency. This study finds a new path that Prussian Blue (PB) ultrathin nanosheet assembly material (PB-NSa) is designed and used to reach efficient catalysis through continuous interaction with ammonium perchlorate (AP, component to be catalyzed). Based on the strong oxidation environment provided by AP, the decomposition of PB occurs in advance, the product Fe2O3 accelerates the decomposition of AP that can release a large amount of gas, then reacts on Fe2O3 and disperses it near the undecomposed AP, finally realizing continuous and efficient catalysis. The results show that under the catalysis of PB-N, “deactivation” stage of AP thermal decomposition disappears, showing two consecutive exothermic stages, high temperature decomposition peak of AP is reduced to 341.1 °C, the reduction range is 73.1 °C. Combining kinetic calculation and TG-IR test, it is found that PB-NSa can keep excellent catalytic stability, which depends on its special structure and interaction with AP. This research provides a design idea for the material to achieve catalytic stability, which will greatly promote its rapid industrialization.

  • Co-author: 

    Ren Zhuoqun,Tang Xiaolin,Zheng Zeyu,Zhang Kuan,Liao Jun

  • Indexed by: 

    Journal paper

  • Correspondence Author: 

    Zhang Yifu*,Huang Chi*

  • Document Code: 

    202300661

  • Discipline: 

    Natural Science

  • First-Level Discipline: 

    Chemistry

  • Document Type: 

    J

  • Volume: 

    33

  • Issue: 

    21

  • Page Number: 

    202300661

  • Translation or Not: 

    no

  • Date of Publication: 

    2023-02-19

  • Links to published journals: 

    https://doi.org/10.1002/adfm.202300661

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