In situ synthesis of ultrafine metal clusters triggered by dodecaborate supramolecular organic frameworks
发布时间:2018-11-03
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- 所属单位:
- 化学与分子科学学院
- 发表刊物:
- Nanoscale
- 刊物所在地:
- 英国
- 摘要:
- Supramolecular nano-assemblies with tunable morphology have attracted extensive attentions in many frontiers and composite materials manufacturing. Herein, a new class of shape-controlled dodecaborate-based supramolecular organic frameworks (BOFs), decorated with diverse ultrafine noble metal clusters (Au, Pd, Pt, Ag), have been successfully fabricated via the tunable host-guest assembly of cucurbit[n=5,6,7,8]uril and Cs2[closo-B12H12]. Benefiting from the unique dodecaborate-cucurbit[n]uril chaotropic effect, a breakthrough has been made in modulating the supramolecular frameworks in the urch
- 论文类型:
- 期刊论文
- 论文编号:
- DOI: 10.1039/C8NR06917D
- 学科门类:
- 理学
- 一级学科:
- 化学
- 文献类型:
- J
- 期号:
- 10
- 页面范围:
- 19846 – 19853
- 是否译文:
- 否
- 发表时间:
- 2018-10-15
- 收录刊物:
- SCI