In situ synthesis of ultrafine metal clusters triggered by dodecaborate supramolecular organic frameworks
发布时间：2018-11-03
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所属单位：化学与分子科学学院
发表刊物：Nanoscale
刊物所在地：英国
摘要：Supramolecular nano-assemblies with tunable morphology have attracted extensive attentions in many frontiers and composite materials manufacturing. Herein, a new class of shape-controlled dodecaborate-based supramolecular organic frameworks (BOFs), decorated with diverse ultrafine noble metal clusters (Au, Pd, Pt, Ag), have been successfully fabricated via the tunable host-guest assembly of cucurbit[n=5,6,7,8]uril and Cs2[closo-B12H12]. Benefiting from the unique dodecaborate-cucurbit[n]uril chaotropic effect, a breakthrough has been made in modulating the supramolecular frameworks in the urch
论文类型：期刊论文
论文编号：DOI: 10.1039/C8NR06917D
学科门类：理学
一级学科：化学
文献类型：J
期号：10
页面范围：19846 – 19853
是否译文：否
发表时间：2018-10-15
收录刊物：SCI