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张海波

副教授

基本信息 / Basic Information

  • 教师英文名称: Haibo Zhang
  • 教师拼音名称: Zhang Haibo
  • 所在单位: 化学与分子科学学院
  • 职务: 化学国家级实验教学示范中心(武汉大学)副主任
  • 学历: 研究生毕业
  • 性别: 男
  • 在职信息: 在职
  • 毕业院校: 武汉大学
  • 学科: 应用化学 、 化学其他专业

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论文成果

当前位置: 武汉大学张海波 - 科学研究 - 论文成果

Efficient hydrolytic dehydrogenation of ammonia borane catalyzed by ultrafine Pt clusters confined in Ni–Ti layered double hydroxides with closo-dodecaborate

发布时间:2024-08-06
点击次数:
DOI码:
10.1016/j.ijhydene.2024.08.007
发表刊物:
International Journal of Hydrogen Energy
摘要:
Ammonia borane (NH3BH3, AB) is a highly promising candidate for hydrogen storage. Nevertheless, there is an urgent need to develop an efficient and stable catalyst that can control hydrogen generation under mild conditions. The use of catalysts with numerous surface atoms anchored to a carrier to achieve a synergistic effect is an appealing approach in catalysis. In this work, a series of highly dispersed metal clusters NiTi-LDH@B12H12@M (M = Au, Pd, Pt, Ag) catalysts were successfully synthesized at room temperature by leveraging the reductivity of [closo-B12H12]2- immobilized in the layered double hydroxide (LDH) laminate, along with the spatial confinement and anion exchange capabilities of LDH. Specifically, utilizing the optimal catalyst NiTi-LDH@B12H12@Pt 2.4% (wt. Pt), the AB hydrolysis reaction exhibited extraordinary catalytic activity. It exhibited a first-order reaction rate with respect to Pt and a near zero-order reaction rate with respect to AB concentration. The AB hydrolysis can be achieved in a mere 29 s at 25 °C with a conversion rate of 100%. The corresponding turnover frequency (TOF) attains a value of 454.06 molH2molPtmin−1, and the apparent activation energy (Ea) is 41.8 kJ mol−1, surpassing numerous previously reported Pt-based catalysts. The outstanding catalytic performance can be ascribed to the uniform distribution of ultrafine Pt clusters, along with the synergistic effect conferred by NiTi-LDH and intercalated anions ([closo-B12H12]2-).
论文类型:
期刊论文
卷号:
82
页面范围:
901-909
是否译文:
发表时间:
2024-08-05
发布期刊链接:
https://doi.org/10.1016/j.ijhydene.2024.08.007